Please use this identifier to cite or link to this item:
http://hdl.handle.net/10174/6042
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| Title: | Characterization of Micro-Mesoporous Materials from Nitrogen and Toluene Adsorption: Experiment and Modeling |
| Authors: | Ravikovitch, PI
Vishnyakov, A
Neimark, AV
Ribeiro Carrott, MML
Russo, PA
Carrott, PJM |
| Keywords: | Chemistry |
| Issue Date: | 2006 |
| Publisher: | American Chemical Society |
| Citation: | Characterization of Micro-Mesoporous Materials from Nitrogen and Toluene Adsorption: Experiment and Modelling, P.I. Ravikovitch, A. Vishnyakov, A.V. Neimark, M.M.L. Ribeiro Carrott, P.A. Russo & P.J.M. Carrott, Langmuir, 22 (2006) 513-516 |
| Abstract: | Universal mechanisms of adsorption and capillary condensation of toluene and nitrogen on ordered MCM-41 and
PHTS materials are studied by means of high-resolution experiments and Monte Carlo molecular simulations. A
molecular simulation model of toluene adsorption in silica nanopores, which accounts for surface heterogeneity, and
a hybrid molecular-macsroscopic method for pore size distribution (PSD) calculations have been developed. For a
range of reference materials, the PSD results obtained from toluene isotherms are consistent with the results of nitrogen
adsorption using the nonlocal density functional theory method. |
| URI: | http://hdl.handle.net/10174/6042 |
| Type: | article |
| Appears in Collections: | CQE - Publicações - Artigos em Revistas Internacionais Com Arbitragem Científica
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CQE - Publicações - Artigos em Revistas Internacionais Com Arbitragem Científica /
