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Title: An “Out-of-the-Box” Example for Heterocyclic Chemistry: Synthesis of 3,6-Bis-(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine
Authors: Mendes, Paulo J.
Silva, Tiago JL
Tomaz, Ana Isabel
Garcia, M. Helena
Editors: Afonso, Carlos A M
Candeias, Nuno R
Simão, Dulce Pereira
Trindade, Alexandre F
Coelho, Jaime A S
Tan, Bin
Franzen, Robert
Keywords: Heterocyclic ring formation
Issue Date: 2017
Publisher: Royal Society of Chemistry
Citation: An “Out-of-the-Box” Example for Heterocyclic Chemistry: Synthesis of 3,6-Bis-(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine, T.J.L. Silva, P.J. Mendes, A.I. Tomaz & M.H. Garcia em Comprehensive Organic Chemistry Experiments for the Laboratory Classroom, C.A.M. Afonso, N.R. Candeias, D. Pereira Simão, A.F. Trindade, J.A.S. Coelho, B. Tan & R. Franzén (Eds.), RSC Publications, Cambridge, 2017, Cap.12.2.5, pp.745-749 (ISBN 978-1-84973-963-4)
Abstract: 3,6-Dissubsituted tetrazines can be included in functional molecular systems for the development of sensors and optical switches, electroactive polymers or solar cells. Tetrazine derivatives, namely dipyridyl-s-tetra- zines and related molecules, have also been frequently used as bridging ligands in metallo-organic compounds. Their N-hydro (di, tetra, hexa) derivatives exhibit biological activity and some have been tested for their anti-tumour activity. This experiment describes a simple procedure for the synthesis of 3,6-bis(3,5-dimethyl-1H- pyrazol-1-yl)-s-tetrazine in moderate yield with a straightforward work-up.
ISBN: 978-1-84973-963-4
Type: bookPart
Appears in Collections:QUI - Publicações - Capítulos de Livros
CQE - Publicações - Capítulos de Livros

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